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FRAGMENTATION OF DEPROTONATED PLUMERAN INDOLE ALKALOIDS BY ELECTROSPRAY IONIZATION TANDEM MASS SPECTROMETRY

The fragmentation of four deprotonated plumeran indole alkaloids (PIAs), namely aspidospermidine (1), demethoxypalosine (2), aspidocarpine (3), and aspidolimine (4), previously isolated from Aspidosperma spruceanum has been investigated by electrospray ionization tandem mass spectrometry (ESI-MS/MS)...

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Principais autores: Yan R. Robles, Ricardo Vessecchi, Ivo J. C. Vieira, Raimundo Braz-Filho, Antonio E. M. Crotti
Format: Artigo
Sprog:Inglês
Udgivet: Sociedade Brasileira de Química 2025-06-01
Serier:Química Nova
Fag:
deprotonated molecule
gas-phase fragmentation reactions
indole alkaloids
negative ion electrospray
Online adgang:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422025000600302&lng=en&tlng=en
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