First application of chiral phosphotriesters in asymmetric metal catalysis: enantioselective Zn-catalyzed hydrosilylation of ketones in the presence of BINOL-derived phosphates

Chiral phosphotriesters are an unexplored class of ligands in metal catalysis. We wish to disclose herein the foremost application of novel chiral BINOL-derived mono- and bisphosphates in asymmetric zinc-catalyzed hydrosilylation of ketones. Corresponding alcohols were obtained in up to 92% yield an...

Volledige beschrijving

Bibliografische gegevens

Hoofdauteurs:	Ngo Ndimba, Alphonsine, Roisnel, Thierry, Argouarch, Gilles, Lalli, Claudia
Formaat:	Artigo
Taal:	Inglês
Gepubliceerd in:	Académie des sciences 2021-03-01
Reeks:	Comptes Rendus. Chimie
Onderwerpen:	Chiral phosphotriesters BINOL Asymmetric catalysis Enantioselective hydrosilylation Ketones
Online toegang:	https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.67/
Tags:	Voeg label toe Geen labels, Wees de eerste die dit record labelt!