First application of chiral phosphotriesters in asymmetric metal catalysis: enantioselective Zn-catalyzed hydrosilylation of ketones in the presence of BINOL-derived phosphates

Chiral phosphotriesters are an unexplored class of ligands in metal catalysis. We wish to disclose herein the foremost application of novel chiral BINOL-derived mono- and bisphosphates in asymmetric zinc-catalyzed hydrosilylation of ketones. Corresponding alcohols were obtained in up to 92% yield an...

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Hlavní autoři:	Ngo Ndimba, Alphonsine, Roisnel, Thierry, Argouarch, Gilles, Lalli, Claudia
Médium:	Artigo
Jazyk:	Inglês
Vydáno:	Académie des sciences 2021-03-01
Edice:	Comptes Rendus. Chimie
Témata:	Chiral phosphotriesters BINOL Asymmetric catalysis Enantioselective hydrosilylation Ketones
On-line přístup:	https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.67/
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