Hypervalent iodine compounds for anti-Markovnikov-type iodo-oxyimidation of vinylarenes

The iodo-oxyimidation of styrenes with the N-hydroxyimide/I2/hypervalent iodine oxidant system was proposed. Among the examined hypervalent iodine oxidants (PIDA, PIFA, IBX, DMP) PhI(OAc)2 proved to be the most effective; yields of iodo-oxyimides are 34–91%. A plausible reaction pathway includes the...

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Bibliographic Details

Main Authors:	Igor B. Krylov, Stanislav A. Paveliev, Mikhail A. Syroeshkin, Alexander A. Korlyukov, Pavel V. Dorovatovskii, Yan V. Zubavichus, Gennady I. Nikishin, Alexander O. Terent’ev
Format:	Artigo
Language:	Inglês
Published:	Beilstein-Institut 2018-08-01
Series:	Beilstein Journal of Organic Chemistry
Subjects:	free radicals hypervalent iodine imide-N-oxyl radicals iodination N-hydroxyimides oxidative functionalization
Online Access:	https://doi.org/10.3762/bjoc.14.188
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