Probing the Electronic Structure of Spectator Oxo Ligands by 17O NMR Spectroscopy

Spectator oxo ligands are ubiquitous in catalysis, in particular in olefin epoxidation and olefin metathesis. Here we use computationally derived 17O NMR parameters to probe the electronic structure of spectator oxo ligands in these two reactions. We show that 17O NMR parameters allow to distinguish...

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Autori principali:	Christopher P. Gordon, Christophe Copéret
Natura:	Artigo
Lingua:	Alemão
Pubblicazione:	Swiss Chemical Society 2020-04-01
Serie:	CHIMIA
Soggetti:	chemical shift tensor nmr spectroscopy olefin epoxidation olefin metathesis spectator oxo ligand
Accesso online:	https://www.ingentaconnect.com/contentone/scs/chimia/2020/00000074/00000004/art00003
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