Dearomatization of 3-Aminophenols for Synthesis of Spiro[chromane-3,1′-cyclohexane]-2′,4′-dien-6′-ones via Hydride Transfer Strategy-Enabled [5+1] Annulations

The Sc(OTf)₃-catalyzed dearomative [5+1] annulations between readily available 3-aminophenols and <i>O</i>-alkyl <i>ortho</i>-oxybenzaldehydes were developed for synthesis of spiro[chromane-3,1′-cyclohexane]-2′,4′-dien-6′-ones. The “two-birds-with-one-stone” strategy was disclosed by the...

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Bibliografische gegevens

Hoofdauteurs:	Jia-Cheng Ge, Yufeng Wang, Feng-Wei Guo, Xiangyun Kong, Fangzhi Hu, Shuai-Shuai Li
Formaat:	Artigo
Taal:	Inglês
Gepubliceerd in:	MDPI AG 2024-02-01
Reeks:	Molecules
Onderwerpen:	dearomatization spiro[chromane-3,1′-cyclohexane]-2′,4′-dien-6′-ones C(sp<sup>3</sup>)–H bond functionalization antifungal activity
Online toegang:	https://www.mdpi.com/1420-3049/29/5/1012
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