Gold-Catalyzed Hydrothiolation of Alkenes and Allenes with Thiols
The reaction mechanism of the gold-catalyzed hydrothiolation of alkenes (<b>1</b>) with thiols (<b>2</b>) has been investigated in detail. The tetranuclear gold complex, (PPh<sub>3</sub>)<sub>4</sub>Au<sub>4</sub>(SPh)<sub>2</sub>(NTf)<sub>2</sub> (<b>A</b>), is a key intermediate in the catalytic h...
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| Hauptverfasser: | , , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
MDPI AG
2026-03-01
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| Schriftenreihe: | Chemistry |
| Schlagworte: | |
| Online-Zugang: | https://www.mdpi.com/2624-8549/8/4/38 |
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