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Gold-Catalyzed Hydrothiolation of Alkenes and Allenes with Thiols

The reaction mechanism of the gold-catalyzed hydrothiolation of alkenes (<b>1</b>) with thiols (<b>2</b>) has been investigated in detail. The tetranuclear gold complex, (PPh<sub>3</sub>)<sub>4</sub>Au<sub>4</sub>(SPh)<sub>2</sub>(NTf)<sub>2</sub> (<b>A</b>), is a key intermediate in the catalytic h...

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Principais autores: Akiya Ogawa, Taichi Tamai, Keiko Fujiwara, Ryo Tanaka, Daichi Kurata, Yuki Yamamoto
Format: Artigo
Jezik:Inglês
Izdano: MDPI AG 2026-03-01
Serija:Chemistry
Teme:
Online dostop:https://www.mdpi.com/2624-8549/8/4/38
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