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Selective hydrolysis of α-oxo ketene N,S-acetals in water: switchable aqueous synthesis of β-keto thioesters and β-keto amides

An eco-friendly selective hydrolysis of chain α-oxo ketene N,S-acetals in water for the switchable synthesis of β-keto thioesters and β-keto amides is reported. In refluxing water, the hydrolysis reactions of α-oxo ketene N,S-acetals in the presence of 1.0 equiv of dodecylbenzenesulfonic acid effect...

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Detalles Bibliográficos
Principais autores: Haifeng Yu, Wanting Zhang, Xuejing Cui, Zida Liu, Xifu Zhang, Xiaobo Zhao
Formato: Artigo
Idioma:Inglês
Publicado: Beilstein-Institut 2024-09-01
Series:Beilstein Journal of Organic Chemistry
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Acceso en liña:https://doi.org/10.3762/bjoc.20.190
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