Copper‐Catalyzed Defluorinative Allylboration of Allenes with Trifluoromethyl Alkenes
An N‐heterocyclic carbene/Cu‐catalyzed coupling of allenes, bis(pinacolato)diboron, and trifluoromethyl alkenes is reported. The method allows access to stereodefined borylated 1,1‐difluoro‐1,5‐dienes with high levels of selectivity. The integration of a 1,5‐diene scaffold with boron and fluorine fu...
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| Hauptverfasser: | , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Wiley-VCH
2026-01-01
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| Schriftenreihe: | ChemistryEurope |
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| Online-Zugang: | https://doi.org/10.1002/ceur.202500296 |
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