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Introducing Weakly Ligated Tris(trifluoromethyl)copper(III)

Abstract Tris(trifluoromethyl)copper(III), Cu(CF3)3, was prepared for the first time and fully characterized in the form of weakly coordinated highly reactive solvent neutral adducts (DMF)2Cu(CF3)3 and (MeCN)Cu(CF3)3. Free Cu(CF3)3 is an elusive molecule of distorted T‐shaped geometry with Lewis aci...

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Principais autores: Dr. Vladimir Motornov, Martin Procházka, Nora Alpuente, Dr. Pedro Salvador, Prof. Petr Slavíček, Dr. Blanka Klepetářová, Prof. Xavi Ribas, Dr. Petr Beier
Formato: Artigo
Idioma:Inglês
Publicado: Wiley-VCH 2024-03-01
Series:ChemistryEurope
Assuntos:
Copper
High-valent copper
Lewis acids
Trifluoromethylation
Oxidation State
Acceso en liña:https://doi.org/10.1002/ceur.202400004
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