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Second Generation Synthesis of the Neo-Clerodane Diterpenoid Methyl Barbascoate

The second generation total synthesis of the neo-clerodane diterpenoid, methyl barbascoate, was accomplished in seven or nine linear steps via double enol triflation and subsequent palladium catalyzed double carbonylation, followed by regioselective samarium diiodide mediated conjugate reduction.

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Detalhes bibliográficos
Principais autores: Hisahiro Hagiwara, Naomi Honma, Kimihiko Kinugawa, Shota Sato, Takashi Hoshi, Toshio Suzuki
Formato: Artigo
Idioma:Inglês
Publicado em: SAGE Publishing 2013-07-01
Colecção:Natural Product Communications
Acesso em linha:https://doi.org/10.1177/1934578X1300800706
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