Second Generation Synthesis of the Neo-Clerodane Diterpenoid Methyl Barbascoate
The second generation total synthesis of the neo-clerodane diterpenoid, methyl barbascoate, was accomplished in seven or nine linear steps via double enol triflation and subsequent palladium catalyzed double carbonylation, followed by regioselective samarium diiodide mediated conjugate reduction.
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| Autori principali: | , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
SAGE Publishing
2013-07-01
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| Serie: | Natural Product Communications |
| Accesso online: | https://doi.org/10.1177/1934578X1300800706 |
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