Synthesis and Characterization of Two Isostructural POCOP Ni(II) Pincer Complexes Containing Fluorothiophenolate Ligands: [Ni(SC<sub>6</sub>F<sub>4</sub>-4-H){C<sub>6</sub>H<sub>2</sub>-3-(C<sub>2</sub>H<sub>3</sub>O)-2,6-(OP<i><sup>i</sup></i>Pr<sub>2</sub>)<sub>2</sub>}] and [Ni(SC<sub>6</sub>F<sub>5</sub>){C<sub>6</sub>H<sub>2</sub>-3-(C<sub>2</sub>H<sub>3</sub>O)-2,6-(OP<i><sup>i</sup></i>Pr<sub>2</sub>)<sub>2</sub>}]
Among their many applications, metal pincer complexes are of interest for their properties as catalysts in cross-coupling reactions. Pincer ligands exhibit tridentate coordination to the metal center and occupy the meridional positions forming two chelate rings. The two Ni(II) POCOP pincer complexes...
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| 主要な著者: | , , , , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
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MDPI AG
2022-05-01
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| シリーズ: | Molbank |
| 主題: | |
| オンライン･アクセス: | https://www.mdpi.com/1422-8599/2022/2/M1359 |
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