Synthesis and Characterization of Two Isostructural POCOP Ni(II) Pincer Complexes Containing Fluorothiophenolate Ligands: [Ni(SC<sub>6</sub>F<sub>4</sub>-4-H){C<sub>6</sub>H<sub>2</sub>-3-(C<sub>2</sub>H<sub>3</sub>O)-2,6-(OP<i><sup>i</sup></i>Pr<sub>2</sub>)<sub>2</sub>}] and [Ni(SC<sub>6</sub>F<sub>5</sub>){C<sub>6</sub>H<sub>2</sub>-3-(C<sub>2</sub>H<sub>3</sub>O)-2,6-(OP<i><sup>i</sup></i>Pr<sub>2</sub>)<sub>2</sub>}]
Among their many applications, metal pincer complexes are of interest for their properties as catalysts in cross-coupling reactions. Pincer ligands exhibit tridentate coordination to the metal center and occupy the meridional positions forming two chelate rings. The two Ni(II) POCOP pincer complexes...
שמור ב:
| Principais autores: | , , , , , , , |
|---|---|
| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
MDPI AG
2022-05-01
|
| סדרה: | Molbank |
| נושאים: | |
| גישה מקוונת: | https://www.mdpi.com/1422-8599/2022/2/M1359 |
| תגים: |
אין תגיות, היה/י הראשונ/ה לתייג את הרשומה!
|
