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Rational design of cyclopropane-based chiral PHOX ligands for intermolecular asymmetric Heck reaction

A novel class of chiral phosphanyl-oxazoline (PHOX) ligands with a conformationally rigid cyclopropyl backbone was synthesized and tested in the intermolecular asymmetric Heck reaction. Mechanistic modelling and crystallographic studies were used to predict the optimal ligand structure and helped to...

Ful tanımlama

Kaydedildi:
Asıl Yazarlar: Marina Rubina, William M. Sherrill, Alexey Yu. Barkov, Michael Rubin
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: Beilstein-Institut 2014-07-01
Seri Bilgileri:Beilstein Journal of Organic Chemistry
Konular:
asymmetric catalysis
chiral phosphine ligands
cyclopropane
Heck reaction
organophosphorus
transition metal catalysis
Online Erişim:https://doi.org/10.3762/bjoc.10.158
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