Asymmetric total synthesis of smyrindiol employing an organocatalytic aldol key step
The first organocatalytic asymmetric synthesis of smyrindiol, by using an (S)-proline catalyzed enantioselective intramolecular aldol reaction as the key step, is described. Smyrindiol was synthesized from commercially available 2,4-dihydroxybenzaldehyde in 15 steps, with excellent stereoselectivity...
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| Auteurs principaux: | , , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Beilstein-Institut
2012-07-01
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| Collection: | Beilstein Journal of Organic Chemistry |
| Sujets: | |
| Accès en ligne: | https://doi.org/10.3762/bjoc.8.123 |
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