Trifluoromethylation of Perfluorinated Diacylfluorides: Synthesis of the Diketone CF3C(O)CF2C(O)CF3 and of New Perfluorinated Diol (CF3)2C(OH)CF2C(OH)(CF3)2

Perfluoromalonyl difluoride reacts with TMS-CF3 (1:1) in the presence of KF to give the new diketone CF2(C(O)CF3)2. A large excess (5:1) of TMS-CF3 results in the presumed potassium dialkoxide [(CF3)2COK]2CF2 which yields the 1,3-ditertiarydiol [(CF3)2C(OH)]2CF2 on reaction with H2SO4.

Detalles Bibliográficos

Principais autores:	Sandra Corti, William T. Pennington, Darryl D. DesMarteau
Formato:	Artigo
Idioma:	Inglês
Publicado:	Slovenian Chemical Society 2013-11-01
Series:	Acta Chimica Slovenica
Assuntos:	Perfluoromalonyl difluoride trifluoromethylated diketone 1 3-ditertiarydiola
Acceso en liña:	https://acsi-journal.eu/index.php/ACSi/article/view/89
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