Trifluoromethylation of Perfluorinated Diacylfluorides: Synthesis of the Diketone CF3C(O)CF2C(O)CF3 and of New Perfluorinated Diol (CF3)2C(OH)CF2C(OH)(CF3)2
Perfluoromalonyl difluoride reacts with TMS-CF3 (1:1) in the presence of KF to give the new diketone CF2(C(O)CF3)2. A large excess (5:1) of TMS-CF3 results in the presumed potassium dialkoxide [(CF3)2COK]2CF2 which yields the 1,3-ditertiarydiol [(CF3)2C(OH)]2CF2 on reaction with H2SO4.
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| Asıl Yazarlar: | , , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
Slovenian Chemical Society
2013-11-01
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| Seri Bilgileri: | Acta Chimica Slovenica |
| Konular: | |
| Online Erişim: | https://acsi-journal.eu/index.php/ACSi/article/view/89 |
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