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Mn⊕-Induced Loss of Ethylene from Gaseous 4-Octyne

The mechanism established for the unimolecular loss of C2H4 from [Fe(4-octyne)]⊕, is somehow altered in the analogous Mn⊕-induced reaction in that some intramolecular hydrogen exchange (involving unprecedented manganese-carbene complexes) precedes the dissociation. Mechanistic variants are discusse...

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Autores principales: Christian Schulze, Helmut Schwarz
Formato: Artigo
Lenguaje:Alemão
Publicado: Swiss Chemical Society 1987-08-01
Colección:CHIMIA
Acceso en línea:https://www.chimia.ch/chimia/article/view/9803
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