Mn⊕-Induced Loss of Ethylene from Gaseous 4-Octyne
The mechanism established for the unimolecular loss of C2H4 from [Fe(4-octyne)]⊕, is somehow altered in the analogous Mn⊕-induced reaction in that some intramolecular hydrogen exchange (involving unprecedented manganese-carbene complexes) precedes the dissociation. Mechanistic variants are discusse...
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| Hoofdauteurs: | , |
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| Formaat: | Artigo |
| Taal: | Alemão |
| Gepubliceerd in: |
Swiss Chemical Society
1987-08-01
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| Reeks: | CHIMIA |
| Online toegang: | https://www.chimia.ch/chimia/article/view/9803 |
| Tags: |
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