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Rhodium-catalysed direct hydroarylation of alkenes and alkynes with phosphines through phosphorous-assisted C−H activation

Dialkyl biaryl phosphines find wide application in catalysis as ligands. Here, the authors report a rhodium-catalysed hydroarylation of alkenes and alkynes with tertiary phosphines through P(III)-chelation assisted C-H activation affording a library of functionalized phosphines which hold potential...

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Autors principals: Dingyi Wang, Ben Dong, Yandong Wang, Jiasheng Qian, Jinjun Zhu, Yue Zhao, Zhuangzhi Shi
Format: Artigo
Idioma:Inglês
Publicat: Nature Portfolio 2019-08-01
Col·lecció:Nature Communications
Accés en línia:https://doi.org/10.1038/s41467-019-11420-5
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