Divergent Reactivity of 2-Vinylpyridine and 1-Vinylpyrazole in Rhodium-Phosphine Systems: C-H Activation and Dinuclear Chemistry
The RhI-RhIII mixed valence dinuclear complex Rh2- Cl2(μ-H)(μ-η2,κ2-C,N-NC5H4-2-(Z)CH=CH)(PPhMe2)3 has been prepared by reaction of [Rh(μ-Cl)(η2-coe)2]2 with 2-vinylpyridine in the presence of dimethylphenylphosphine as a result of C-H activation of the terminal olefinic proton. The X-ray structure...
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| Publicat a: | Journal of the Mexican Chemical Society |
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| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Sociedad Química de México
2017
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| Matèries: | |
| Accés en línia: | https://www.redalyc.org/articulo.oa?id=47552182009 |
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