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Vanadium(V)-Substitution Reactions of Wells–Dawson-Type Polyoxometalates: From [X2M18O62]6− (X = P, As; M = Mo, W) to [X2VM17O62]7−

The formation processes of V(V)-substituted polyoxometalates with the Wells–Dawson-type structure were studied by cyclic voltammetry and by 31P NMR and Raman spectroscopy. Generally, the vanadium-substituted heteropolytungstates, [P2VW17O62]7− and [As2VW17O62]7−, were prepared by mixing equimolar a...

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שמור ב:
Principais autores: Tadaharu Ueda, Yuriko Nishimoto, Rie Saito, Miho Ohnishi, Jun-ichi Nambu
פורמט: Artigo
שפה:Inglês
יצא לאור: MDPI AG 2015-07-01
סדרה:Inorganics
נושאים:
polyoxometalate
Wells–Dawson
vanadium
substitution
גישה מקוונת:http://www.mdpi.com/2304-6740/3/3/355
תגים: הוספת תג
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