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Vanadium(V)-Substitution Reactions of Wells–Dawson-Type Polyoxometalates: From [X2M18O62]6− (X = P, As; M = Mo, W) to [X2VM17O62]7−

The formation processes of V(V)-substituted polyoxometalates with the Wells–Dawson-type structure were studied by cyclic voltammetry and by 31P NMR and Raman spectroscopy. Generally, the vanadium-substituted heteropolytungstates, [P2VW17O62]7− and [As2VW17O62]7−, were prepared by mixing equimolar a...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Tadaharu Ueda, Yuriko Nishimoto, Rie Saito, Miho Ohnishi, Jun-ichi Nambu
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: MDPI AG 2015-07-01
Cyfres:Inorganics
Pynciau:
Mynediad Ar-lein:http://www.mdpi.com/2304-6740/3/3/355
Tagiau: Ychwanegu Tag
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