Rhodium-Catalyzed <i>Trans</i>-Bis-Silylation Reactions of 2-Ethynyl-3-pentamethyldisilanylpyridines

Rhodium-catalyzed reactions of 2-ethynyl-3-pentamethyldisilanylpyridine derivatives (<b>1</b> and <b>2</b>) are reported. The reactions of compounds <b>1</b> and <b>2</b> in the presence of catalytic amounts of rhodium complexes at 110 °C gave the corresponding pyridine-fused siloles (<b>3</b>) and...

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Autors principals:	Akinobu Naka, Hisayoshi Kobayashi
Format:	Artigo
Idioma:	Inglês
Publicat:	MDPI AG 2023-04-01
Col·lecció:	Molecules
Matèries:	rhodium-catalyzed reaction <i>trans</i>-bis-silylation silole DFT calculation 2-ethynyl-3-pentamethyldisilanylpyridine cyclic silicon compound
Accés en línia:	https://www.mdpi.com/1420-3049/28/8/3284
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