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Access to Enantiomerically Pure <i>P</i>-Chiral 1-Phosphanorbornane Silyl Ethers

Sulfur-protected enantiopure <i>P</i>-chiral 1-phosphanorbornane silyl ethers <b>5a</b>,<b>b</b> are obtained in high yields via the reaction of the hydroxy group of <i>P</i>-chiral 1-phosphanorbornane alcohol <b>4</b> with <i>tert</i>-butyldimethylsilyl chloride (TBDMSCl) and triphenylsilyl chlorid...

Deskribapen osoa

Gorde:
Egile Nagusiak: Kyzgaldak Ramazanova, Soumyadeep Chakrabortty, Fabian Kallmeier, Nadja Kretzschmar, Sergey Tin, Peter Lönnecke, Johannes G. de Vries, Evamarie Hey-Hawkins
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: MDPI AG 2023-08-01
Saila:Molecules
Gaiak:
asymmetric hydrogenation
enantiopure
<i>P</i>-chiral phosphines
silylation
Sarrera elektronikoa:https://www.mdpi.com/1420-3049/28/17/6210
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