Alkali‐Metal Mediation: Diversity of Applications in Main‐Group Organometallic Chemistry

por Gentner, Thomas X., Mulvey, Robert E.
Publicado en Angew Chem Int Ed Engl (2020)

Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans‐Metal‐Trapping

por Uzelac, Marina, Kennedy, Alan R., Hevia, Eva, Mulvey, Robert E.
Publicado en Angew Chem Int Ed Engl (2016)

Synergic Transformation of an Ethylenediamine to a Lithium 1,3-Diaza-2-zincacyclopentene via an Alkyllithium/Bis(alkyl)zinc Mixture

por Campbell, Ross, García-Álvarez, Pablo, Kennedy, Alan R, Mulvey, Robert E
Publicado 2010

Structural Diversity in Alkali Metal and Alkali Metal Magnesiate Chemistry of the Bulky 2,6‐Diisopropyl‐N‐(trimethylsilyl)anilino Ligand

por Fuentes, M. Ángeles, Zabala, Andoni, Kennedy, Alan R., Mulvey, Robert E.
Publicado en Chemistry (2016)

Developing a Hetero-Alkali-Metal Chemistry of 2,2,6,6-Tetramethyl-piperidide (TMP): Stoichiometric and Structural Diversity within a Series of Lithium/Sodium, Lithium/Potassium and...

por Armstrong, David R, Kennedy, Alan R, Mulvey, Robert E, Robertson, Stuart D
Publicado 2011

LiTMP Trans‐Metal‐Trapping of Fluorinated Aromatic Molecules: A Comparative Study of Aluminum and Gallium Carbanion Traps

por McLellan, Ross, Uzelac, Marina, Kennedy, Alan R., Hevia, Eva, Mulvey, Robert E.
Publicado en Angew Chem Int Ed Engl (2017)

Structurally Stimulated Deprotonation/Alumination of the TMP Anion**

por Conway, Ben, Kennedy, Alan R, Mulvey, Robert E, Robertson, Stuart D, Álvarez, Joaquin García
Publicado en Angew Chem Int Ed Engl (2010)

catena-Poly[sodium-μ(2)-(N,N,N′,N′-tetra­methyl­ethane-1,2-diamine)-κ(2) N:N′-sodium-bis­[μ(2)-bis­(trimethyl­sil­yl)aza­nido-κ(2) N:N]]

por Kennedy, Alan R., Mulvey, Robert E., O’Hara, Charles T., Robertson, Stuart D., Robertson, Gemma M.
Publicado 2012

Mixed Lithium Amide–Lithium Halide Compounds: Unusual Halide-Deficient Amido Metal Anionic Crowns**

por Kennedy, Alan R, Mulvey, Robert E, O'Hara, Charles T, Robertson, Gemma M, Robertson, Stuart D
Publicado 2011

Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reactio...

por Clegg, William, Conway, Ben, Hevia, Eva, McCall, Matthew D., Russo, Luca, Mulvey, Robert E.
Publicado 2009

Modifying Alkylzinc Reactivity with 2,2′-Dipyridylamide: Activation of tBu=Zn Bonds for para-Alkylation of Benzophenone**

por Armstrong, David R, Garden, Jennifer A, Kennedy, Alan R, Mulvey, Robert E, Robertson, Stuart D
Publicado en Angew Chem Int Ed Engl (2013)

Lithium Dihydropyridine Dehydrogenation Catalysis: A Group 1 Approach to the Cyclization of Diamine Boranes

por McLellan, Ross, Kennedy, Alan R., Orr, Samantha A., Robertson, Stuart D., Mulvey, Robert E.
Publicado en Angew Chem Int Ed Engl (2016)

1‐Alkali‐metal‐2‐alkyl‐1,2‐dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications

por McLellan, Ross, Kennedy, Alan R., Mulvey, Robert E., Orr, Samantha A., Robertson, Stuart D.
Publicado en Chemistry (2017)

Comparing Neutral (Monometallic) and Anionic (Bimetallic) Aluminum Complexes in Hydroboration Catalysis: Influences of Lithium Cooperation and Ligand Set

por Pollard, Victoria A., Fuentes, M. Ángeles, Kennedy, Alan R., McLellan, Ross, Mulvey, Robert E.
Publicado en Angew Chem Int Ed Engl (2018)

Solvation Effects on the Structure and Stability of Alkali Metal Carbenoids

por Dilchert, Katharina, Schmidt, Michelle, Großjohann, Angela, Feichtner, Kai‐Stephan, Mulvey, Robert E., Gessner, Viktoria H.
Publicado en Angew Chem Int Ed Engl (2020)

Lithium‐Aluminate‐Catalyzed Hydrophosphination Applications

por Pollard, Victoria A., Young, Allan, McLellan, Ross, Kennedy, Alan R., Tuttle, Tell, Mulvey, Robert E.
Publicado en Angew Chem Int Ed Engl (2019)

Expected and Unexpected Reactivities of Homoleptic LiNacNac and Heteroleptic NacNacMg(TMP) β-Diketiminates toward Various Small Unsaturated Organic Molecules

por Gauld, Richard M., Lynch, Jennifer R., Kennedy, Alan R., Barker, Jim, Reid, Jacqueline, Mulvey, Robert E.
Publicado en Inorg Chem (2021)

Alkali-Metal-Mediated Manganation(II) of Functionalized Arenes and Applications of ortho-Manganated Products in Pd-Catalyzed Cross-Coupling Reactions with Iodobenzene

por Blair, Victoria L, Clegg, William, Conway, Ben, Hevia, Eva, Kennedy, Alan, Klett, Jan, Mulvey, Robert E, Russo, Luca
Publicado 2008

Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation

por Armstrong, David R, Balloch, Liam, Hevia, Eva, Kennedy, Alan R, Mulvey, Robert E, O'Hara, Charles T, Robertson, Stuart D
Publicado 2011

Structural Tracking of the Potassium-Mediated Magnesiation of Anisole

por Clegg, William, Conway, Ben, García-Álvarez, Pablo, Kennedy, Alan R, Mulvey, Robert E, Russo, Luca, Sassmannshausen, Jörg, Tuttle, Tell
Publicado 2009