Efficient and Practical Synthesis of syn- and anti-b,g- Dihydroxyphosphonates Derived from (S)-Mandelic Acid

A new efficient and practical synthesis of syn- and antib,g-dihydroxyphosphonates 1 and 2 was developed in high diastereoselectivityvia reduction of b-ketophosphonates readily obtainedfrom (S)-mandelic acid. An example of “diastereoselective 1,2-induction”is showed and a mechanistic model to explain...

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Detalhes bibliográficos
Publicado no:Journal of the Mexican Chemical Society
Main Authors: Haydée Rojas Cabrera, Joana Ochoa Morales, Emanuel Hernández Núñez, Mario Fernández Zertuche, Mario Ordóñez
Formato: Artigo
Idioma:Inglês
Publicado em: Sociedad Química de México 2007
Assuntos:
Química
(S)
induction
mandelic acid
ketophosphonates
Diastereoselective 1
Acesso em linha:https://www.redalyc.org/articulo.oa?id=47551413
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