Evidence for a Strained Cyclic Allene in the Ring Closure Reaction of Enynylketenes
We show in this paper using HF and MP2 ab initio calculationsthat the ring closure of 5 generates an intermediate best describedas the closed-shell cyclic allene 6a, instead of the usually assumeddiradical nature reported in the literature. This intermediate thengives rise to the formation of 7. The...
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| Publicado en: | Journal of the Mexican Chemical Society |
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| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Sociedad Química de México
2002
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| Materias: | |
| Acceso en línea: | https://www.redalyc.org/articulo.oa?id=47546211 |
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