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Synthesis of New Chiral Monosulfonamides Prepared from (11R,12R)- 11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene and their Use as Ligands for Asymmetric Catalysis

New chiral monosulfonamides 6-16 containing (11R,12R)- diamino-9,10-dihydro-9,10-ethanoanthracene as carbon skeleton were prepared. Compounds 6-12, 15 and 16 were used as optically active ligands in the enantioselective ethylation of benzaldehyde. Moreover, the monosulfonamides 6-10 were tested i...

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Detalhes bibliográficos
Publicado no:Journal of the Mexican Chemical Society
Principais autores: Gabriela Huelgas, Haydee Rojas Cabrera, Domingo Madrigal, Ratnasamy Somanathan, Pilar Guzmán, Aurelio Ortiz, Cecilia Anaya de Parrodi
Formato: Artigo
Idioma:Inglês
Publicado em: Sociedad Química de México 2013
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Acesso em linha:https://www.redalyc.org/articulo.oa?id=47527412011
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