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Stereochemical Studies on the Addition of Allylsilanes to Aldehydes. The SE´ Component

Model compounds ul-1 and lk-1 have been studied to determine both the position of the silicon electrofuge and the relative orientation of the double bonds in the transition structure of the allylmetal- aldehyde condensation. The use of the deuterium label allows an unbiased assessment of the syn ver...

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Bibliographic Details
Published in:Journal of the Mexican Chemical Society
Main Authors: Scott E. Denmark, Neil G. Almstead
Format: Artigo
Language:Inglês
Published: Sociedad Química de México 2009
Subjects:
Online Access:https://www.redalyc.org/articulo.oa?id=47512154016
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