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A New Method to prepare an e,e,e Trisadduct of C60 Using a Protection- Deprotection Sequence

A racemic mixture of the e,e,e Bingel-trisadduct, tris[di(ethoxycarbonyl)methano] [60]fullerene 3 was synthesized by malonate additions (Bingel reaction) following by retro Diels-Alder reactions using a C60 tris-e,e,e adduct of anthracene 1 as precursor. Using this approach, the anthracenes act as p...

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Publicado en:Journal of the Mexican Chemical Society
Principais autores: Álvaro Duarte-Ruiz, Luis Echegoyen, Adriana Aya, Fernando Gómez-Baquero
Formato: Artigo
Idioma:Inglês
Publicado: Sociedad Química de México 2009
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Acceso en liña:https://www.redalyc.org/articulo.oa?id=47512154015
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