Hydride-Meisenheimer Complex Formation and Protonation as Key Reactions of 2,4,6-Trinitrophenol Biodegradation by Rhodococcus erythropolis

Biodegradation of 2,4,6-trinitrophenol (picric acid) by Rhodococcus erythropolis HLPM-1 proceeds via initial hydrogenation of the aromatic ring system. Here we present evidence for the formation of a hydride-Meisenheimer complex (anionic ς-complex) of picric acid and its protonated form under physio...

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Hlavní autoři: Rieger, Paul-Gerhard, Sinnwell, Volker, Preuß, Andrea, Francke, Wittko, Knackmuss, Hans-Joachim
Médium: Artigo
Jazyk:Inglês
Vydáno: American Society for Microbiology 1999
Témata:
Physiology and Metabolism
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC93496/
https://ncbi.nlm.nih.gov/pubmed/9973345
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