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Efficient Bulky Organo-Zinc Scorpionates for the Stereoselective Production of Poly(rac-lactide)s
The direct reaction of the highly sterically demanding acetamidinate-based NNN′-scorpionate protioligand Hphbp(t)amd [Hphbp(t)amd = N,N′-di-p-tolylbis(3,5-di-tertbutylpyrazole-1-yl)acetamidine] with one equiv. of ZnMe(2) proceeds in high yield to the mononuclear alkyl zinc complex [ZnMe(κ(3)-phbp(t)...
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| Publicado no: | Polymers (Basel) |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
MDPI
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8309543/ https://ncbi.nlm.nih.gov/pubmed/34301114 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/polym13142356 |
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