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Silver-Catalyzed Enantioselective Propargylic C–H Bond Amination Through Rational Ligand Design
Asymmetric C–H amination via nitrene transfer is a powerful tool to prepare enantioenriched amine precursors from abundant C–H bonds. Herein, we report a regio- and enantioselective synthesis of γ-alkynyl γ-aminoalcohols via a silver-catalyzed propargylic C–H amination. The protocol was enabled by a...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2020
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8294079/ https://ncbi.nlm.nih.gov/pubmed/32659081 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c05726 |
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