Mechanistic study of photocatalytic CO(2) reduction using a Ru(ii)–Re(i) supramolecular photocatalyst

Supramolecular photocatalysts comprising [Ru(diimine)(3)](2+) photosensitiser and fac-[Re(diimine)(CO)(3){OC(O)OC(2)H(4)NR(2)}] catalyst units can be used to reduce CO(2) to CO with high selectivity, durability and efficiency. In the presence of triethanolamine, the Re catalyst unit efficiently take...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Kamogawa, Kei, Shimoda, Yuushi, Miyata, Kiyoshi, Onda, Ken, Yamazaki, Yasuomi, Tamaki, Yusuke, Ishitani, Osamu
Format: Artigo
Sprog:Inglês
Udgivet: The Royal Society of Chemistry 2021
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8294001/
https://ncbi.nlm.nih.gov/pubmed/34349939
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc02213j
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