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Oxidative Addition of Aryl and Alkyl Halides to a Reduced Iron Pincer Complex

The two-electron oxidative addition of aryl and alkyl halides to a reduced iron dinitrogen complex with a strong-field tridentate pincer ligand has been demonstrated. Addition of iodobenzene or bromobenzene to (3,5-Me(2)(Mes)CNC)Fe(N(2))(2) (3,5-Me(2)(Mes)CNC = 2,6-(2,4,6-Me-C(6)H(2)-imidazol-2-ylid...

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Pubblicato in:J Am Chem Soc
Autori principali: Rummelt, Stephan M., Peterson, Paul O., Zhong, Hongyu, Chirik, Paul J.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2021
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8293301/
https://ncbi.nlm.nih.gov/pubmed/33829769
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c01486
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