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Asymmetric Total Synthesis of the Naturally Occurring Antibiotic Anthracimycin
The first total synthesis of the potent antibiotic anthracimycin was achieved in 20 steps. The synthesis features an intramolecular Diels–Alder reaction to forge the trans-decalin moiety, and an unprecedented aldol reaction using a complex β-ketoester to provide the tricarbonyl motif. A Stork–Zhao o...
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| Publicado en: | Org Lett |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8283552/ https://ncbi.nlm.nih.gov/pubmed/32598151 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c01913 |
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