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Capillary Ionization and Jumps of Capacitive Energy Stored in Mesopores

[Image: see text] We study ionic liquid–solvent mixtures in slit-shaped nanopores wider than a few ion diameters. Using a continuum theory and generic thermodynamic reasoning, we reveal that such systems can undergo a capillary ionization transition. At this transition, the pores spontaneously ioniz...

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Bibliografiske detaljer
Udgivet i:J Phys Chem C Nanomater Interfaces
Main Authors: Cruz, Carolina, Kondrat, Svyatoslav, Lomba, Enrique, Ciach, Alina
Format: Artigo
Sprog:Inglês
Udgivet: American Chemical Society 2021
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8282200/
https://ncbi.nlm.nih.gov/pubmed/34276858
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcc.1c00624
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