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Absolute configuration retention of a configurationally labile ligand during dynamic processes of thiolate protected gold clusters
Monolayer protected metal clusters are dynamic nanoscale objects. For example, the chiral Au(38)(2-PET)(24) cluster (2-PET: 2-phenylethylthiolate) racemizes at moderate temperature. In addition, ligands and metal atoms can easily exchange between clusters. Such processes are important for applicatio...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
The Royal Society of Chemistry
2021
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8278927/ https://ncbi.nlm.nih.gov/pubmed/34349915 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01702k |
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