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Changing the Reactivity of Zero‐ and Mono‐Valent Germanium with a Redox Non‐Innocent Bis(silylenyl)carborane Ligand
Using the chelating C,C′‐bis(silylenyl)‐ortho‐dicarborane ligand, 1,2‐(RSi)(2)‐1,2‐C(2)B(10)H(10) [R=PhC(NtBu)(2)], leads to the monoatomic zero‐valent Ge complex (“germylone”) 3. The redox non‐innocent character of the carborane scaffold has a drastic influence on the reactivity of 3 towards reduct...
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| Gepubliceerd in: | Angew Chem Int Ed Engl |
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| Hoofdauteurs: | , , , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
John Wiley and Sons Inc.
2021
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| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8252802/ https://ncbi.nlm.nih.gov/pubmed/33909944 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202103769 |
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