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Rhoda‐Electrocatalyzed Bimetallic C−H Oxygenation by Weak O‐Coordination

Rhodium‐electrocatalyzed arene C−H oxygenation by weakly O‐coordinating amides and ketones have been established by bimetallic electrocatalysis. Likewise, diverse dihydrooxazinones were selectively accessed by the judicious choice of current, enabling twofold C−H functionalization. Detailed mechanis...

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Publicat a:Angew Chem Int Ed Engl
Autors principals: Tan, Xuefeng, Massignan, Leonardo, Hou, Xiaoyan, Frey, Johanna, Oliveira, João C. A., Hussain, Masoom Nasiha, Ackermann, Lutz
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2021
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8252749/
https://ncbi.nlm.nih.gov/pubmed/33651910
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202017359
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