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Zeolite‐Stabilized Di‐ and Tetranuclear Molybdenum Sulfide Clusters Form Stable Catalytic Hydrogenation Sites
Supercages of faujasite (FAU)‐type zeolites serve as a robust scaffold for stabilizing dinuclear (Mo(2)S(4)) and tetranuclear (Mo(4)S(4)) molybdenum sulfide clusters. The FAU‐encaged Mo(4)S(4) clusters have a distorted cubane structure similar to the FeMo‐cofactor in nitrogenase. Both clusters posse...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8252740/ https://ncbi.nlm.nih.gov/pubmed/33576131 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202015769 |
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