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Selective and Additive‐Free Hydrogenation of Nitroarenes Mediated by a DMSO‐Tagged Molecular Cobalt Corrole Catalyst

We report on the first cobalt corrole that effectively mediates the homogeneous hydrogenation of structurally diverse nitroarenes to afford the corresponding amines. The given catalyst is easily assembled prior to use from 4‐tert‐butylbenzaldehyde and pyrrole followed by metalation of the resulting...

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Detalhes bibliográficos
Publicado no:European J Org Chem
Main Authors: Timelthaler, Daniel, Schöfberger, Wolfgang, Topf, Christoph
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8252576/
https://ncbi.nlm.nih.gov/pubmed/34248412
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.202100073
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