A Stable Homoleptic Divinyl Tetrelene Series

The synthesis of the new bulky vinyllithium reagent ((Me)IPr=CH)Li, ((Me)IPr=[(MeCNDipp)(2)C]; Dipp=2,6‐iPr(2)C(6)H(3)) is reported. This vinyllithium precursor was found to act as a general source of the anionic 2σ, 2π‐electron donor ligand [(Me)IPr=CH](−). Furthermore, a high‐yielding route to the...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Roy, Matthew M. D., Baird, Samuel R., Dornsiepen, Eike, Paul, Lucas A., Miao, Linkun, Ferguson, Michael J., Zhou, Yuqiao, Siewert, Inke, Rivard, Eric
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
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Full Papers
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8252546/
https://ncbi.nlm.nih.gov/pubmed/33848023
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202100969
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