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New Noncentrosymmetric Tetrel Pnictides Composed of Square‐Planar Gold(I) with Peculiar Bonding

Three novel isostructural equiatomic gold tetrel pnictides, AuSiAs, AuGeP, and AuGeAs, were synthesized and characterized. These phases crystallize in the noncentrosymmetric (NCS) monoclinic space group Cc (no. 9), featuring square‐planar Au within cis‐[AuTt(2)Pn(2)] units (Tt=tetrel, Si, Ge; Pn=pni...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Lee, Shannon J., Won, Juyeon, Wang, Lin‐Lin, Jing, Dapeng, Harmer, Colin P., Mark, Justin, Akopov, Georgiy, Kovnir, Kirill
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8251799/
https://ncbi.nlm.nih.gov/pubmed/33523500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202005312
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