Iron‐Catalyzed Wacker‐type Oxidation of Olefins at Room Temperature with 1,3‐Diketones or Neocuproine as Ligands

Herein, we describe a convenient and general method for the oxidation of olefins to ketones using either tris(dibenzoylmethanato)iron(III) [Fe(dbm)(3)] or a combination of iron(II) chloride and neocuproine (2,9‐dimethyl‐1,10‐phenanthroline) as catalysts and phenylsilane (PhSiH(3)) as additive. All r...

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發表在:Angew Chem Int Ed Engl
Main Authors: Puls, Florian, Linke, Philipp, Kataeva, Olga, Knölker, Hans‐Joachim
格式: Artigo
語言:Inglês
出版: John Wiley and Sons Inc. 2021
主題:
Research Articles
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC8251641/
https://ncbi.nlm.nih.gov/pubmed/33856090
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202103222
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