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Protected amino acids as a nonbonding source of chirality in induction of single-handed screw-sense to helical macromolecular catalysts
Chiral nonbonding interaction with N-protected amino acid methyl esters used as chiral additives in achiral solvents allows dynamic induction of single-handed helical conformation in poly(quinoxaline-2,3-diyl)s (PQX) bearing only achiral substituents. Ac-l-Pro-OMe, for instance, allows induction of...
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| Publicat a: | Chem Sci |
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| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
The Royal Society of Chemistry
2021
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8246299/ https://ncbi.nlm.nih.gov/pubmed/34257881 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01764k |
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