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Helix-mediated over 1 nm-range chirality recognition by ligand-to-ligand interactions of dinuclear helicates

Long-range chirality recognition between the two chiral guest ligands can be tuned based on the helix distances (d(Ln–Ln) = 11.5 and 14.0 Å) of bis-diketonate bridged dinuclear lanthanide complexes (2Th and 3Th, respectively) used as mediators. Both 2Th and 3Th form one-dimensional (1D) helical stru...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Suko, Natsumi, Itamoto, Hideki, Okayasu, Yoshinori, Okura, Naoya, Yuasa, Junpei
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8246085/
https://ncbi.nlm.nih.gov/pubmed/34257874
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01611c
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